Carbenes. Pincers, chelates, and abnormal binding modes
نویسندگان
چکیده
منابع مشابه
Carbenes . Pincers , chelates , and abnormal binding modes *
Routes to pincer and chelate carbene complexes of Pd, Rh, and Ir include double geminal CH activation, metallation, and CH activation. Abnormal binding via imidazole C5 can occur, and ion pairing can strongly influence C2 vs. C5 binding. Prior ligand binding via pyridine N before metallation is not essential. Computational methods are used extensively, for example, to compare N vs. C binding in...
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ژورنال
عنوان ژورنال: Pure and Applied Chemistry
سال: 2003
ISSN: 1365-3075,0033-4545
DOI: 10.1351/pac200375040435